用于厚屏蔽小探测器的蒙特卡罗模拟减方差方法研究

反应堆屏蔽计算中经常出现厚屏蔽、小探测器问题，常规蒙特卡罗方法难以有效解决。基于自动重要抽样（AIS）方法，本文提出了小探测器自动重要抽样(SDAIS)方法，并针对小探测器问题，优化了AIS方法的虚粒子赌分裂算法。该方法在自主开发的蒙特卡罗屏蔽程序MCShield上进行了实现。使用NUREG/CR-6115 PWR基准题验证该方法的正确性和计算效率。结果表明，SDAIS方法可有效地解决厚屏蔽小探测器问题，相比AIS方法及传统的重要性方法，计算效率提升1~2个量级。     

利用数值模拟方法研究树脂裂解反应器的进气结构

利用数值模拟的方法,考察了树脂裂解反应器上部进气方式的效果,发现存在空气利用率低的问题,同时空气还会带走反应器内的大量热量,削弱树脂裂解反应区域的温度,由此证明了试验推论的正确性。同时,利用数值模拟的方法,对设备进气方式进行优化改进:当采用下部进气后,空气的利用率得到明显的提升,空气分布也较为均匀。但此时,空气对反应区域内温度的削弱作用也更为明显。此外,随着设备进气口直径的减小和进气口数量的增加,能够较为明显地提高树脂反应区域的空气分布均匀度,而提升设备的加热功率,对提高反应区域内的温度有显著的作用。     

钴/镍复合中间层真空扩散连接钨与钢

以钴粉/镍箔为复合中间层，采用800，900和1 000 ℃等三种连接温度，加压10 MPa并保温120 min的工艺条件，对钨/钢真空扩散连接. 研究了接头的微观组织、成分分布、力学性能及断口特征. 结果表明，连接温度为800 ℃和900 ℃时，钨/中间层界面金属间化合物生成很少，对应接头抗剪强度分别为186 MPa和172 MPa，断口均位于钨母材中近界面的位置，为典型解理断裂形貌；当连接温度升至1 000 ℃时，钨/中间层界面生成厚度小于2 μm的连续金属间化合物层，接头抗剪强度降至115 MPa，断裂也发生在钨母材中近界面的位置，断口大部分区域为沿晶断裂特征.     

玉米秸秆衍生碳基固体酸的制备及其催化纤维素水解糖化

以玉米秸秆为原料，通过碳化-磺化法制备了碳基固体酸（CSA），采用XRD、FTIR、XPS、SEM、阳离子交换与返滴定法等手段对其结构形貌进行表征，并考察了制备条件对固体酸表面活性基团含量与催化活性的影响。以NaOH/尿素冻融预处理后的纤维素为底物，研究了CSA催化纤维素水解糖化的效果与条件。结果表明：NaOH/尿素冻融预处理能够有效辅助固体酸催化纤维素水解，在350℃碳化2h、100℃磺化5h条件下制备的CSA催化性能最好，其酸量达3.94mmol/g，其中磺酸基、羧基、酚羟基含量分别为1.09mmol/g、1.36mmol/g、1.49mmol/g。在m(CSA)∶m(纤维素)=3∶1、水解温度200℃、水解时间为0.5h的条件下，纤维素水解还原糖得率与转化率分别为47.1%和63%。CSA循环利用3次催化活性下降不大。本研究可为废弃生物质原料制备的固体酸催化纤维素水解转化利用提供科学参考。     

基于VMD与KFCM的柴油机故障诊断算法

针对柴油机的故障诊断问题，提出了一种基于变分模态分解（variational mode decomposition，简称VMD）与核模糊C均值聚类算法（kernel fuzzy C-means clustering，简称KFCM）联合的故障诊断方法。首先，针对VMD算法中分解层数K的选择问题进行了自适应优化；然后，从优化VMD算法的分解结果中选取3个关键分量计算最大奇异值，并将其作为3维的特征向量输入KFCM算法中进行分类识别；最后，对仿真信号以及某型柴油机的模拟故障实验信号使用优化VMD、传统VMD和经验模态分解（empirical mode decomposition，简称EMD）方法分别进行分解与识别。结果表明，笔者提出的方法明显改善了模态混叠现象，提高了模式识别的诊断正确率，提出的联合算法具有更好的应用前景。     

Right Way of Using Graphene Oxide Additives for Water-Lubricated PEEK: Adding in Polymer or Water?

Water-lubricated polymer is attracting more and more interest from the industry. Adding nanoparticles is considered to be an effective way to improve the tribological performance. In this work, water-lubricated Polyetheretherketone (PEEK)-steel contacts were employed as the objects of study. A careful comparative study was made by investigating the effect of adding graphene oxide (GO) into water or into PEEK. Results show that adding GO into water can significantly reduce the wear and friction coefficient of pure PEEK, which is much more effective than adding GO into PEEK. Under the lubrication of GO aqueous dispersion, the wear of PEEK remains very low even under a harsh condition where the pressure reaches 50 MPa and the linear sliding speed is 0.7 m/s. Neat PEEK and GO/PEEK composites in pure water exhibit serious wear under this harsh condition. The excellent lubricating properties of GO aqueous dispersion are attributed to GO nanosheets entering into solid contacts, which can not only form a protective layer on steel counterpart repairing the worn surface, but also strongly adhere to the PEEK matrix resulting in an in situ-formed GO coating and prevent the scratch by steel counterpart.     

The efficiency and comparison of novel techniques for cell wall disruption in astaxanthin extraction from Haematococcus pluvialis

The efficiency of various techniques pulsed electric field (PEF), ultrasound (US), high‐pressure microfluidisation (HPMF), hydrochloric acid (HCl) and ionic liquids (ILs) for cell wall disruption in astaxanthin extraction from Haematococcus pluvialis was compared. The results indicated that ILs, HCl and HPMF treatment were shown the most efficient for cell disruption with more than 80% astaxanthin recovery. While the cell wall integrity of H. pluvialis cyst cell was less affected by US and PEF treatment. It was found that imidazolium‐based ILs showed the greater potential for cell disruption than pyridinium‐based and ammonium‐based ILs. Among all the ILs examined, 1‐butyl‐3‐methylimidazolium chloride ([Bmim] Cl) exhibited efficient cell disruption and capability of astaxanthin recovery at mild condition (pretreatment with 40% IL aqueous solution at 40 °C, followed by extraction with methanol at 50 °C) without extensive energy consumption and special facility requirement. In addition, recyclability of ILs was excellent.     

面向长距离量子通信的双光子关联成像技术

量子时域鬼成像利用光子对的时间-频率关联性实现了50km光纤链路上的图像传送,有望应用于量子通信的协议中。然而,现有方案的成像质量较差,成像速度较慢,因此其应用性在一定程度上受到了限制。文章对已有成像方案进行了较大的改进,利用可编程滤波器数字设定待成像信息,进而实现了二维图像信息的自动化实时传送。实验结果证明,改进方案的成像质量和速度均有显著改善,有利于推动量子关联成像在量子通信领域的应用。     

激光立体成形TC4钛合金的热力场演化

激光立体成形能够实现高性能复杂零件的精确成形，但成形过程中的高温度梯度极易导致残余应力和变形，最终影响构件的几何精度和力学性能。通过搭建基板单边夹持原位热变形测量系统，探究了多道多层TC4钛合金成形件在激光立体成形过程中基板温度、变形的演化规律，分析了不同扫描策略对构件热应力场的影响。研究结果表明，构件的变形发展受其热历史驱使，扫描策略对成形件的热变形具有显著影响。     

Catalytic hydrogenation of CO2 from 600 MW supercritical coal power plant to produce methanol: A techno-economic analysis

Electricity and water from renewable hydropower plant are used as input for electrolysis unit to generate hydrogen, while CO₂ is captured from 600 MW supercritical coal power plant using post-combustion chemical solvent based technology. The captured CO₂ and H₂ generated through electrolysis are used to synthesize methanol through catalytic thermo-chemical reaction. The methanol synthesis plant is designed, modeled and simulated using commercial software Aspen Plus^®. The reactor is analyzed for two widely adopted kinetic models known as Graaf model and Vanden-Bossche (VB) model to predict the methanol yield and CO₂ conversion. The results show that the methanol reactor based on Graaf kinetic model produced 0.66 tonne of methanol per tonne of CO₂ utilized which is higher than that of the VB kinetic model where 0.6 tonne of methanol is produced per tonne of CO₂ utilized. The economic analysis reveals that 1.2 billion USD annually is required at the present cost of both H₂ production and CO₂ abatement to utilize continuous emission of 3.2 million tonne of CO₂ annually from 600 MW supercritical coal power unit to synthesize methanol. However, sensitivity analysis indicates that methanol production becomes feasible by adopting anyone of the route such as by increasing methanol production rate, by reducing levelised cost of hydrogen production, by reducing CO₂ mitigation cost or by increasing the current market selling price of methanol and oxygen.